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The most important cash crop in Colonial America was tobacco, first cultivated by the English at their Jamestown Colony of Virginia in 1610 CE by the merchant John Rolfe (l
13 C NMR spectrum, 153.2 is attributed to the presence of C at position 2 of the 1,3,4-thiadiazole moiety, 144.0 is attributed to the presence of C at position 4 of the substituted benzene ring, 133.2 is attributed to the presence of C at the amide, 129.8 is attributed to the presence of C at positions 3 and 5 of the substituted benzene ring, 129.0 is attributed to the presence of C at positions 2 and 6 of the substituted benzene ring and 21.7 is attributed to the presence of C at -CH 3
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