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It does not extend beyond it

The use of a methyl group is optimum in that it is small enough to not influence the overall activity of the molecule, while the rationale behind the location of the modification is to protect the most common degradation location of the peptides, i.e., the peptide bond

doi:10.1002/bit.260400806 Santos LO, Gonzales TA, Ubeda BT, Monte Alegre R (2007) Influence of culture conditions on glutathione production by Saccharomyces cerevisiae